The Mesoproterozoic basement in the southern Baltic Sea: insights from the G 14–1 off-shore borehole     

Karsten?ObstEmail author  J?rg?Hammer  Gerhard?Katzung  Dietmar?Korich 《International Journal of Earth Sciences》2004,93(1):1-12

The continuation of the Mesoproterozoic basement of the southern Fennoscandian Shield is documented in the G 14–1 off-shore borehole, northeast of the island of Rügen, where crystalline rocks of monzogranitic composition occur beneath flat-lying early Palaeozoic sediments at a depth of approximately 2,000 m. The greenish-grey, or partly reddish-grey, granites show a slightly porphyritic texture marked by plagioclase crystals or aggregates in a groundmass dominated by fresh microcline. Chloritized biotite occurs as a subordinate mafic phase. Ductile and brittle deformation is indicated by a weak foliation and the occurrence of several cataclastic zones, respectively. Major and trace element geochemistry suggest that these rocks are K-rich calc-alkaline granites and represent a restite-poor melting product of a granodioritic protolith. The low MgO, Cr, Ni and Co concentrations and relatively high content of accessory phases (apatite, zircon) point to formation of water undersaturated, high temperature (>900 °C) melts at low degrees of partial melting. Although the G 14 granite lacks hornblende, in contrast to most of the granites from Bornholm, it seems geochemically related to them. Analysed samples mostly fit an intermediate position between the Rønne and Vang granitoids, which both belong to a group of Mesoproterozoic intrusions showing partial ductile deformation. (Y+Nb) vs. Rb plots suggest that all these granitic rocks were generated in intracratonic conditions. A genetic relationship between them and contemporaneously intruded Karlshamn-group granites in Blekinge, eastern Scania and Småland is supported by intrusion age of 1,460±3 Ma obtained from Pb-Pb isotope ratios measured on single zircons of the G 14 granite.  相似文献   

Global Warming and the Summertime Evapotranspiration Regime of the Alpine Region   总被引：1，自引：0，他引：1  

Pierluigi Calanca  Andreas Roesch  Karsten Jasper  Martin Wild 《Climatic change》2006,79(1-2):65-78

Changes of the summer evapotranspiration regime under increased levels of atmospheric greenhouse gases are discussed for three Alpine river basins on the basis of a new set of simulations carried out with a high-resolution hydrological model. The climate change signal was inferred from the output of two simulations with a state-of-the-art global climate model (GCM), a reference run valid for 1961–1990 and a time-slice simulation valid for 2071–2100 under forcing from the A2 IPCC emission scenario. In this particular GCM experiment and with respect to the Alpine region summer temperature was found to increase by 3 to 4 ^∘C, whereas precipitation was found to decrease by 10 to 20%. Global radiation and water vapor pressure deficit were found to increase by about 5% and 2 hPa, respectively. On this background, an overall increase of potential evapotranspiration of about 20% relative to the baseline was predicted by the hydrological model, with important variations between but also within individual basins. The results of the hydrological simulations also revealed a reduction in the evapotranspiration efficiency that depends on altitude. Accordingly, actual evapotranspiration was found to increase at high altitudes and to the south of the Alps, but to decrease in low elevation areas of the northern forelands and in the inner-Alpine domain. Such a differentiation does not appear in the GCM scenario, which predicts an overall increase in evapotranspiration over the Alps. This underlines the importance of detailed simulations for the quantitative assessment of the regional impact of climate change on the hydrological cycle.  相似文献   

The importance of alternative conceptual models for simulation of concentrations in a multi-aquifer system     

Lars Troldborg  Jens Christian Refsgaard  Karsten Høgh Jensen  Peter Engesgaard 《Hydrogeology Journal》2007,15(5):843-860

Four different conceptual models based on alternative geological interpretations were formulated for a shallow 600 km² aquifer system in Denmark comprising Quaternary deposits. Each of the four models was calibrated against groundwater heads and discharge measurements through inverse modeling. Subsequently, the transport capabilities of the four models were compared to 32 concentration measurements of environmental tracers (tritium ³H, helium-3 ³He, chlorofluorocarbons CFC11, CFC12 and CFC113). The flow simulations showed only minor differences in spatial head distribution associated with alternative conceptualizations despite the complexity of the aquifer system and the significant differences in geological interpretations. The models, however, showed major differences in predictions of the age of the groundwater and environmental tracer concentrations, differences that are seen as an effect of model structure uncertainty, because no additional calibrations to these data were performed. A single conceptualization may be adequate in characterizing the natural behavior of a field system after calibration, because the calibration procedure is able to compensate for errors in the data or in the conceptual model through biased parameter values. However, once extrapolation beyond the calibration base is attempted, different conceptual model formulations result in significantly different results. Consequently, it is crucial to take model conceptual uncertainty into account when making predictions beyond the calibration base.  相似文献   

Advection-Dispersion Analysis of Solute Transport in Undisturbed Soil Monoliths     

Karsten Høgh Jensen  Georgia Destouni  Mona Sassner 《Ground water》1996,34(6):1090-1097

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DMS oxidation and turbulent transport in the marine boundary layer: A numerical study     

Karsten Suhre  Robert Rosset 《Journal of Atmospheric Chemistry》1994,18(4):379-395

DMS oxidation in the marine boundary layer has been simulated with a mesoscale meteorological model including detailed physical parameterizations. The impact of vertical turbulent transport on the DMS and SO₂ diurnal cycles with and without in-cloud SO₂ oxidation has been studied in a one-dimensional version of the model and compared to results obtained with a zero-dimensional box model. Initialisation has been done using balanced values issued from the imposed sea-air fluxes, dry deposition fluxes and chemical source/sink terms. Particular emphasis has been put on the important role played by evolving vertical mixing in the marine boundary layer.  相似文献   

Crystal field transitions in Co2[Al4Si5]O18 cordierite and CoAl2O4 spinel determined by neutron spectroscopy     

Björn Winkler  Mark J. Harris  Roger S. Eccleston  Karsten Knorr  Bernard Hennion 《Physics and Chemistry of Minerals》1997,25(1):79-82

Inelastic magnetic neutron scattering has been used to determine the energy of the ⁴ A ₂→⁴ T ₂ transition in CoAl₂O₄ spinel and the δ₁ transition in Co₂[Al₄Si₅]O₁₈ cordierite. The observed crystal field splitting in Co-spinel is 485 meV (3900 cm⁻¹), which corresponds to a crystal field stabilization energy of 56.2 kJmol⁻¹. The transition energy of the δ₁ transition in Co-cordierite has been determined to be 21 meV (170 cm⁻¹). The present data demonstrate that magnetic neutron scattering can be used to measure crystal field transitions at energies of interest in the study of 3d-containing silicates. It may be used to measure transition energies when the use of optical spectroscopy is inappropriate. Received: 30 January 1997 / Accepted: 5 July 1997  相似文献   

The crustal role of the Agulhas Plateau, southwest Indian Ocean: evidence from seismic profiling   总被引：2，自引：1，他引：2  

Karsten Gohl  Gabriele Uenzelmann-Neben 《Geophysical Journal International》2001,144(3):632-646

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Olivine [100] normal to foliation: lattice preferred orientation in prograde garnet peridotite formed at high H<Subscript>2</Subscript>O activity,Cima di Gagnone (Central Alps)     

Katrine?Frese  Volkmar?TrommsdorffEmail author  Karsten?Kunze 《Contributions to Mineralogy and Petrology》2003,145(1):75-86

Automated electron backscattered diffraction (EBSD) was applied using a scanning electron microscope to obtain lattice preferred orientation (LPO) data for olivine in garnet peridotites of the Central Alps. As a reference frame, the LPOs of enstatite were also investigated. In the garnet peridotite at Cima di Gagnone (CDG), a weak foliation carrying a distinct lineation is present. The lineation is characterized by elongated enstatite, olivine and poikiloblastic garnet. Olivine shows a very unusual LPO with [100] normal to foliation and [001] parallel to lineation. Achsenverteilungsanalyse (AVA) maps demonstrate that [001] of olivine grains corresponds quite well to their maximum length axes which are preferentially parallel to the lineation. Numerous planar hydrous defects within (001) planes of olivine are marked by palisades of ilmenite rods and show a preferred orientation normal to lineation. Calculated P-wave velocities for CDG are fastest (8.32 km s^у) normal to foliation with a relatively low anisotropy (2.9%). Compared to mantle peridotites with the usual (010)[100] LPO where the fastest Vp direction is towards the lineation, the relationship between flow geometry and seismic anisotropy is significantly different at CDG. Several mechanisms for the formation of the LPO type at CDG are considered, with glide possible on (100)[001] of olivine. On the basis of field data as well as petrographic and petrologic evidence, it has been demonstrated that the CDG garnet peridotite formed by prograde metamorphism from a hydrous protolith at pressures and temperatures of about 3.0 GPa and 750 °C, respectively. The CDG LPO is interpreted to have formed during hydrous subduction zone metamorphism. The same interpretation may hold for the previously investigated olivine LPO at Alpe Arami, which is similar to that at the nearby CDG. The observed anomalous LPO is no proof for ultradeep (>3.0 GPa) conditions.  相似文献   

Ion microprobe studies of water in silicate melts. Concentration-dependent water diffusion in obsidian     

J.R. Delaney  J.L. Karsten 《Earth and Planetary Science Letters》1981,52(1):191-202

The ion microprobe at Johnson Space Center has been calibrated for in situ water determinations on a 10-μm scale over the range 0.2 wt.% H₂O to 1.8, 6.8, and 3.7 wt.%, for basaltic, albitic, and rhyolitic glasses, respectively. The basalt glass calibration curve differs substantially from those of albite and rhyolite glasses, indicating a need to carefully match composition and/or melt structure between H₂O standards and unknowns.A value for the diffusivity of water as a function of concentration and time has been calculated from water diffusion profiles measured in rhyolite glasses prepared at 850°C and 700 barsP_t(H₂O) [1]. Transient diffusion into a semi-infinite medium is described by the equation:?(φ/2)?¸/?φ=?(D_w?¸/?φ)/?φ #x003B8;=1, φ=0, θ→ 0, θ→∞, wherex =distance from the cylinder edge,t =time,C₀ =initial concentration,C_s =concentration at the edge,C =concentration at x,θ = C ? C₀/C_s ? C₀,φ = x/t^1/2, andD_w =diffusivity of water. An iterative technique has been used to calculate solutions to the diffusion equation as a function ofD_w [2]. Comparison of these solutions with the ion probe data indicate that, for0.2wt.% ≤ C ≤ 3.7wt.%H₂O,D_w can be described by an exponential function of θ, of the formD_w = D₀exp(bθ), withD₀ (i.e.,D_w at 0.2%) = (0.8?2.2) × 10^?8 cm²/s and2 ≤ b ≤ 4.  相似文献   

Ion microprobe studies of water in silicate melts: Temperature-dependent water diffusion in obsidian     

J.L. Karsten  J.R. Holloway  J.R. Delaney 《Earth and Planetary Science Letters》1982,59(2):420-428

The temperature dependence of water diffusivity in rhyolite melts over the range 650–950°C and [P_T(H₂O] = 700 bars is evaluated from water concentration-distance profiles measured in glass with an ion microprobe. Diffusivities are exponentially dependent on concentration over this temperature range and vary from about 10^?8 cm²/s at 650°C to about 10^?7 cm²/s at 950°C at 2 wt.% water. Water solubility also varies with temperature at a rate of ?0.14 wt. per 100°C increase. The avtivation energy (E_a) appears to be constant at 19 ± 1kal/mole for 1, 2,and 3 wt.% H₂O. Comparison of these data with results for cation diffusion indicates that this value is a minimum E_a for diffusion of any species in a rhyolite melt.Compensation plots of log₁₀D₀ (the frequency factor) versus E_a indicate that hydrous rhyolite melts follow the same trend as anhydrous basalts. D₀ increases for H₂O and Ca²⁺ [1] as E_a decreases. This suggests that these molecules may diffuse by different mechanisms than do monovalent cations, and that hydration of the melt affects diffusion of Ca²⁺ and H₂O differently than it does monovalent cation diffusion. The results imply that dramatic increases in cation diffusivities by hydration [1] may occur with additions of less than 1 wt.% H₂O.  相似文献